Volume 41 Issue 6
Jun.  2022
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Yubin Hu. Temperature coefficient of seawater pH as a function of temperature, pH, DIC and salinity[J]. Acta Oceanologica Sinica, 2022, 41(6): 114-118. doi: 10.1007/s13131-021-1955-3
Citation: Yubin Hu. Temperature coefficient of seawater pH as a function of temperature, pH, DIC and salinity[J]. Acta Oceanologica Sinica, 2022, 41(6): 114-118. doi: 10.1007/s13131-021-1955-3

Temperature coefficient of seawater pH as a function of temperature, pH, DIC and salinity

doi: 10.1007/s13131-021-1955-3
Funds:  The National Natural Science Foundation of China under contract No. 41806094; the Young Scholars Program of Shandong University under contract No. 2018WLJH43.
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  • Corresponding author: E-mail: yubinhu@sdu.edu.cn
  • Received Date: 2021-06-21
  • Accepted Date: 2021-10-20
  • Available Online: 2022-04-20
  • Publish Date: 2022-06-16
  • pH is a measure of the hydrogen ion activity in a solution, which is a function of temperature. Under normal seawater conditions, it is well constrained. Nowadays, with an increasing interest in complex environments (e.g., sea ice), a better understanding of the temperature change on pH under extreme conditions is needed. The objective of this paper was to investigate the temperature coefficient of the seawater pH (∆pH/∆T) over a wide range of temperature, pH, dissolved inorganic carbon (DIC) and salinity by a method of continuous pH measurement with the temperature change, and to verify the application of CO2SYS for pH conversion under extreme conditions (on the National Bureau of Standards (NBS) scale and the total proton scale). Both experimental results and CO2SYS calculations showed that ∆pH/∆T was slightly affected by temperature over the range of 0°C to 40°C and by pH (at 25°C) from 7.8 to 8.5. However, when pH was out of this range, ∆pH/∆T varied greatly with pH value. According to the experimental results, changes in DIC from 1 mmol/kg to 5 mmol/kg and salinity from 20 to 105 had no significant effect on ∆pH/∆T. CO2SYS calculations showed a slight increase in ∆pH/∆T with DIC on both the NBS scale and the total proton scale; and underestimated ∆pH/∆T at high salinity (i.e., beyond the oceanographic range) on the NBS scale. Nevertheless, CO2SYS is still suitable for pH conversion even under extreme conditions by simply setting the input values of DIC and salinity in CO2SYS within the oceanographic range (e.g., DIC=2 mmol/kg and S=35).
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  • [1]
    Barron J J, Ashton C, Geary L. 2005. The effects of temperature on pH measurement. TSP-01, County Clare, Ireland: Technical Services Department, Reagecon Diagnostics Ltd, Shannon Free Zone, 1–7
    Ben-Yaakov S. 1970. A method for calculating the in situ pH of seawater. Limnology and Oceanography, 15(2): 326–328. doi: 10.4319/lo.1970.15.2.0326
    Dickson A G. 1990. Standard potential of the reaction: AgCl(s) + 1/2H2(g) = Ag(s) + HCl(aq), and the standard acidity constant of the ion ${\rm{HSO}}_4^− $ in synthetic sea water from 273.15 to 318.15 K. Journal of Chemical Thermodynamics, 22(2): 113–127. doi: 10.1016/0021-9614(90)90074-Z
    Dickson A G, Millero F J. 1987. A comparison of the equilibrium constants for the dissociation of carbonic acid in seawater media. Deep-Sea Research Part A: Oceanographic Research Papers, 34(10): 1733–1743,
    Dickson A G, Sabine C L, Christian J R E. 2007. Guide to best practices for ocean CO2 measurements. http://www.ioccp.org/index.php/documents/standards-and-methods/2-uncategorised/263-guide-to-best-practices-for-ocean-co2-measurements [2019-09-10]
    Doney S C, Fabry V J, Feely R A, et al. 2009. Ocean acidification: the other CO2 problem. Annual Review of Marine Science, 1: 169–192. doi: 10.1146/annurev.marine.010908.163834
    Easley R A, Byrne R H. 2012. Spectrophotometric calibration of pH electrodes in seawater using purified m-cresol purple. Environmental Science & Technology, 46(9): 5018–5024. doi: 10.1021/es300491s
    Fabry V J, McClintock J B, Mathis J T, et al. 2009. Ocean acidification at high latitudes: The bellwether. Oceanography, 22(4): 160–171. doi: 10.5670/oceanog.2009.105
    Feely R A, Doney S C, Cooley S R. 2009. Ocean acidification: Present conditions and future changes in a high-CO2 world. Oceanography, 22(4): 36–47. doi: 10.5670/oceanog.2009.95
    Gieskes J M. 1969. Effect of temperature on the pH of seawater. Limnology and Oceanography, 14(5): 679–685. doi: 10.4319/lo.1969.14.5.0679
    Gleitz M, Loeff M R V D, Thomas D N, et al. 1995. Comparison of summer and winter inorganic carbon, oxygen and nutrient concentrations in Antarctic sea ice brine. Marine Chemistry, 51(2): 81–91. doi: 10.1016/0304-4203(95)00053-T
    Hare A A, Wang Feiyue, Barber D, et al. 2013. pH evolution in sea ice grown at an outdoor experimental facility. Marine Chemistry, 154: 46–54. doi: 10.1016/j.marchem.2013.04.007
    Hunter K A. 1998. The temperature dependence of pH in surface seawater. Deep-Sea Research Part I: Oceanographic Research Papers, 45(11): 1919–1930. doi: 10.1016/S0967-0637(98)00047-8
    IPCC. 2014. Climate Change 2013—The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge: Cambridge University Press, 1535
    Kadis R, Leito I. 2010. Evaluation of the residual liquid junction potential contribution to the uncertainty in pH measurement: A case study on low ionic strength natural waters. Analytica Chimica Acta, 664(2): 129–135. doi: 10.1016/j.aca.2010.02.007
    Lui Hon-Kit, Chen Chen-Tung Arthur. 2017. Reconciliation of pH25 and pHinsitu acidification rates of the surface oceans: A simple conversion using only in situ temperature. Limnology and Oceanography: Methods, 15(3): 328–335. doi: 10.1002/lom3.10170
    Marion G M, Millero F J, Camães M F, et al. 2011. pH of seawater. Marine Chemistry, 126(1–4): 89–96. doi: 10.1016/j.marchem.2011.04.002
    Mehrbach C, Culberson C H, Hawley J E, et al. 1973. Measurement of the apparent dissociation constants of carbonic acid in seawater at atmospheric pressure. Limnology and Oceanography, 18(6): 897–907. doi: 10.4319/lo.1973.18.6.0897
    Middelboe A L, Hansen P J. 2007. High pH in shallow-water macroalgal habitats. Marine Ecology Progress Series, 338: 107–117. doi: 10.3354/meps338107
    Millero F J. 1979. The thermodynamics of the carbonate system in seawater. Geochimica et Cosmochimica Acta, 43(10): 1651–1661. doi: 10.1016/0016–7037(79)90184–4
    Millero F J. 2006. Chemical Oceanography. 3rd ed. Boca Raton: CRC Press, 62
    Orr J C, Fabry V J, Aumont O, et al. 2005. Anthropogenic ocean acidification over the twenty-first century and its impact on calcifying organisms. Nature, 437(7059): 681–686. doi: 10.1038/nature04095
    Papadimitriou S, Loucaides S, Rérolle V, et al. 2016. The measurement of pH in saline and hypersaline media at sub-zero temperatures: Characterization of Tris buffers. Marine Chemistry, 184: 11–20. doi: 10.1016/j.marchem.2016.06.002
    Pierrot D E, Lewis E, Wallace D W R. 2006. MS Excel program developed for CO2 system calculations. Oak Ridge, Tennessee: Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U. S. Department of Energy,
    Steinacher M, Joos F, Frölicher T L, et al. 2009. Imminent ocean acidification in the Arctic projected with the NCAR global coupled carbon cycle-climate model. Biogeosciences, 6(4): 515–533. doi: 10.5194/bg-6-515-2009
    Uppström L R. 1974. The Boron/chlorinity ratio of deep-sea water from the Pacific Ocean. Deep-Sea Research and Oceanographic Abstracts, 21(2): 161–162. doi: 10.1016/0011-7471(74)90074-6
    Van Alstyne K L, Nelson T A, Ridgway R L. 2015. Environmental chemistry and chemical ecology of “green tide” seaweed blooms. Integrative and Comparative Biology, 55(3): 518–532. doi: 10.1093/icb/icv035
    Yamamoto-Kawai M, McLaughlin F A, Carmack E C, et al. 2009. Aragonite undersaturation in the Arctic Ocean: Effects of ocean acidification and sea ice melt. Science, 326(5956): 1098–1100. doi: 10.1126/science.1174190
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