YU Tan, PAN Delu, BAI Yan, HE Yijun, LI Dawei, LIANG Chao. A quantitative evaluation of the factors influencing the air-sea carbon dioxide transfer velocity[J]. Acta Oceanologica Sinica, 2016, 35(11): 68-78. doi: 10.1007/s13131-016-0949-z
Citation: YU Tan, PAN Delu, BAI Yan, HE Yijun, LI Dawei, LIANG Chao. A quantitative evaluation of the factors influencing the air-sea carbon dioxide transfer velocity[J]. Acta Oceanologica Sinica, 2016, 35(11): 68-78. doi: 10.1007/s13131-016-0949-z

A quantitative evaluation of the factors influencing the air-sea carbon dioxide transfer velocity

doi: 10.1007/s13131-016-0949-z
  • Received Date: 2015-10-01
  • Rev Recd Date: 2016-03-11
  • The numerous factors influencing the air-sea carbon dioxide (CO2) transfer velocity have been discussed for many years, yet the contributions of various factors have undergone little quantitative estimation. To better understand the mechanism of air-sea transfer, the effects of different factors are discussed on the air-sea transfer velocity and the various parametric models describing the phenomenon are classified and compared. Then, based on GAS EX-98 and ASGAMAGE data, wind models are evaluated and the effects of some factors are discussed quantitatively, including bubbles, waves, wind and so on by considering their interaction through a piecewise average approach. It is found that the air-sea CO2 transfer velocity is not only the function of the wind speed, but is also affected by bubbles, wave parameters and other factors. Stepwise and linear regressions are used. When considering the wind speed, bubbles mediated and the significant wave height, the root mean square error is reduced from 34.53 cm/h to 16.96 cm/h. Discussing the various factors quantitatively can be useful in future assessments of a large spatial scale and long-term air-sea CO2 flux and global change.
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  • Abril G, Commarieu M V, Sottolichio A, et al. 2009. Turbidity limits gas exchange in a large macrotidal estuary. Estuarine, Coastal and Shelf Science, 83(3):342-348
    Bock E J, Hara T, Frew N M, et al. 1999. Relationship between air-sea gas transfer and short wind waves. Journal of Geophysical Research:Oceans, 104(C11):25821-25831
    Bogucki D, Carr M E, Drennan W M, et al. 2010. Preliminary and novel estimates of CO2 gas transfer using a satellite scatterometer during the 2001GasEx experiment. International Journal of Remote Sensing, 31(1):75-92, doi: 10.1080/01431160902882546
    Broecker W S, Peng T H, Ostlund G, et al. 1985. The distribution of bomb radiocarbon in the ocean. Journal of Geophysical Research, 90(C4):6953-6970
    Cember R. 1989. Bomb radiocarbon in the Red Sea:a medium-scale gas exchange experiment. Journal of Geophysical Research, 94(C2):2111-2123
    Chen Liqi, Gao Zhongyong, Yang Xulin, et al. 2004. Prospects of research on carbon cycle in the arctic. Chinese Journal of Polar Research (in Chinese), 16(3):171-180
    Chen Shangji, Ma Jirui. 1991. Marine Data Processing Analysis Method and Its Application (in Chinese). Beijing:China Ocean Press
    Csanady G T. 1990. The role of breaking wavelets in air-sea gas transfer. Journal of Geophysical Research, 95(C1):749-759
    Deacon E L. 1977. Gas transfer to and across an air-water interface. Tellus, 29(4):363-374
    Fairaill C W, Hare J E, Edson J B, et al. 2000. Parameterization and micrometeorological measurement of air-sea gas transfer. Boundary-Layer Meteorology, 96(1-2):63-106, doi: 10.1023/a:1002662826020
    Falkowski P, Scholes R J, Boyle E, et al. 2000. The global carbon cycle:a test of our knowledge of earth as a system. Science, 290(5490):291-296
    Fangohr S, Woolf D K. 2007. Application of new parameterizations of gas transfer velocity and their impact on regional and global marine CO2 budgets. Journal of Marine Systems, 66(1-4):195-203
    Fangohr S, Woolf D K, Jeffery C D, et al. 2008. Calculating long-term global air-sea flux of carbon dioxide using scatterometer, passive microwave, and model reanalysis wind data. Journal of Geophysical Research:Oceans, 113(C9):C09032, doi: 10.1029/2005JC003376
    Frankignoulle M. 1988. Field measurements of air-sea CO2 exchange. Limnology and Oceanography, 33(3):313-322
    Frew N M, Bock E J, Schimpf U, et al. 2004. Air-sea gas transfer:its dependence on wind stress, small-scale roughness, and surface films. Journal of Geophysical Research:Oceans, 109(C8):C08S17, doi: 10.1029/2003JC002131
    Frew N M, Glover D M, Bock E J, et al. 2007. A new approach to estimation of global air-sea gas transfer velocity fields using dual-frequency altimeter backscatter. Journal of Geophysical Research:Oceans, 112(C11):C11003, doi: 10.1029/2006JC003819
    Glover D M, Frew N M, McCue S J. 2007. Air-sea gas transfer velocity estimates from the Jason-1 and TOPEX altimeters:prospects for a long-term global time series. Journal of Marine Systems, 66(1-4):173-181
    Goddijn-Murphy L, Woolf D K, Callaghan A H, et al. 2015. A reconciliation of empirical and mechanistic models of the air-sea gas transfer velocity. Journal of Geophysical Research:Oceans, 121(1):818-835
    Hare J E, Fairall C W, McGillis W R, et al. 2004. Evaluation of the national oceanic and atmospheric administration/coupled-ocean atmospheric response experiment (NOAA/COARE) air-sea gas transfer parameterization using GasEx data. Journal of Geophysical Research:Oceans, 109(C8):C08S11
    Ho D T, Law C S, Smith M J, et al. 2006. Measurements of air-sea gas exchange at high wind speeds in the Southern Ocean:implications for global parameterizations. Geophysical Research Letters, 33(16):L16611
    Jähne B, Münnich K O, Bösinger R, et al. 1987. On the parameters influencing air-water gas exchange. Journal of Geophysical Research:Oceans, 92(C2):1937-1949
    Jeffery C D, Robinson I S, Woolf D K. 2010. Tuning a physically-based model of the air-sea gas transfer velocity. Ocean Modelling, 31(1-2):28-35
    Liss P S, Merlivat L. 1986. Air-sea gas exchange rates:introduction and synthesis. In:Buat-Ménard P, ed. The Role of Air-Sea Exchange in Geochemical Cycling. Dordrecht, Holland:D. Reidel Publishing Company, 113-127
    Mørk E T, Sørensen L L, Jensen B, et al. 2014. Air-sea CO2 gas transfer velocity in a shallow estuary. Boundary-Layer Meteorology, 151(1):119-138
    McGillis W R, Edson J B, Hare J E, et al. 2001. Direct covariance airsea CO2 fluxes. Journal of Geophysical Research:Oceans, 106(C8):16729-16745
    McGillis W R, Edson J B, Zappa C J, et al. 2004. Air-sea CO2 exchange in the equatorial Pacific. Journal of Geophysical Research:Oceans, 109(C8):C08S02
    McNeil C, D'Asaro E. 2007. Parameterization of air-sea gas fluxes at extreme wind speeds. Journal of Marine Systems, 66(1-4):110-121
    Nightingale P D, Malin G, Law C S, et al. 2000. in situ evaluation of air-sea gas exchange parameterizations using novel conservative and volatile tracers. Global Biogeochemical Cycles, 14(1):373-387
    Rutgersson A, Smedman A. 2010. Enhanced air-sea CO2 transfer due to water-side convection. Journal of Marine Systems, 80(1-2):125-134
    Sarmiento J L, Le Quéré C. 1996. Oceanic carbon dioxide uptake in a model of century-scale global warming. Science, 274(5291):1346-1350
    Soloviev A V, Schlüssel P. 1994. Parameterization of the cool skin of the ocean and of the air-ocean gas transfer on the basis of modeling surface renewal. Journal of Physical Oceanography, 24(6):1339-1346
    Sweeney C, Gloor E, Jacobson A R, et al. 2007. Constraining global air-sea gas exchange for CO2 with recent bomb 14C measurements. Global Biogeochemical Cycles, 21(2):GB2015
    Takahashi T, Sutherland S C, Wanninkhof R, et al. 2009. Climatological mean and decadal change in surface ocean pCO2, and net sea-air CO2 flux over the global oceans. Deep Sea Research:Part Ⅱ. Tropical Studies in Oceanography, 56(8-10):554-577
    Wang Aifang. 2006. Mean square slope based on frequency spectrum and its relationship with gas transfer velocity (in Chinese)[dissertation]. Qingdao:Ocean University of China
    Wang Gengchen, Wen Yupu. 1996. Concentration and Emission Monitoring of Greenhouse Gases and Their Relative Processes(in Chinese). Beijing:China Environmental Science Press
    Wanninkhof R. 1985. Kinetic fractionation of the carbon isotopes 13C and 12C during transfer of CO2 from air to seawater. Tellus:B, 37B(3):128-135
    Wanninkhof R. 1992. Relationship between wind speed and gas exchange over the ocean. Journal of Geophysical Research:Oceans, 97(C5):7373-7382
    Wanninkhof R, McGillis W R. 1999. A cubic relationship between airsea CO2 exchange and wind speed. Geophysical Research Letters, 26(13):1889-1892
    Wanninkhof R, Asher W E, Ho D T, et al. 2009. Advances in quantifying air-sea gas exchange and environmental forcing. Annual Review of Marine Science, 1(1):213-244
    Weiss A, Kuss J, Peters G, et al. 2007. Evaluating transfer velocitywind speed relationship using a long-term series of direct eddy correlation CO2 flux measurements. Journal of Marine Systems, 66(1-4):130-139
    Woolf D K. 1993. Bubbles and the air-sea transfer velocity of gases. Atmosphere-Ocean, 31(4):517-540
    Woolf D K. 1997. Bubbles and their role in gas exchange. In:Liss P S, Duce R A, eds. The Sea Surface and Global Change. Cambridge, United Kingdom:Cambridge University Press, 173-205
    Woolf D K. 2005. Parametrization of gas transfer velocities and seastate-dependent wave breaking. Tellus B, 57(2):87-94
    Yu Tan, He Yijun, Yan Xiaohai. 2013. Global air-sea surface carbon dioxide transfer velocity and flux estimated using 17 a altimeter data and a new algorithm. Acta Oceanologica Sinica, 32(10):24-33
    Yu Tan, He Yijun, Zha Guozhen, et al. 2013. Global air-sea surface carbon-dioxide transfer velocity and flux estimated using ERS-2 data and a new parametric formula. Acta Oceanologica Sinica, 32(7):78-87
    Yu Tan, He Yijun, Song Jinbao, et al. 2014. Uncertainty in air-sea CO2 flux due to transfer velocity. International Journal of Remote Sensing, 35(11-12):4340-4370
    Zappa C J, Asher W E, Jessup A T. 2001. Microscale wave breaking and air-water gas transfer. Journal of Geophysical Research:Oceans, 106(C5):9385-9391
    Zappa C J, McGillis W R, Raymond P A, et al. 2007. Environmental turbulent mixing controls on airwater gas exchange in marine and aquatic systems. Geophysical Research Letters, 34(10):L10601
    Zhao Dongliang, Xie Lian. 2010. A practical bi-parameter formula of gas transfer velocity depending on wave states. Journal of Oceanography, 66(5):663-671
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